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1. CH4 + Cl2 光照 CH3Cl + HCl 2. CH3Cl + Cl2 CH2Cl2 + HCl 3. CH2Cl + Cl2 CHCl3 + HCl 4. CHCl3 + Cl2 CCl4+ HCl 5. CH4 高温 C +2H2

6. C16H34 C8H18 + C8H16

加热、加压 催化剂

光照 光照 光照

7. CH3COONa + NaOH CaO CH4↑+ Na2CO3

△

8. CH2 = CH2 + Br2 CH2Br—CH2Br 9. CH2 = CH2 + H2O CH3CH2OH

CH—CHBr 10. CH2 = CH2 + HBr 催化剂 32

△ 催化剂 11. CH2 = CH2 + H2 催化剂 CH3—CH3

△ 催化剂 12. nCH2 = CH2 [ CH2—CH2 ] n

13. nCH2=CH-CH=CH2 [CH2-CH=CH-CH 2] n 14. 2CH2 = CH2 + O2 2CH3CHO 15. CH≡CH + Br2 CHBr = CHBr 16. CHBr = CHBr+ Br2 CHBr2－CHBr2 17. CH≡CH + HCl 催化剂 △ H2C = CHCl 18. nCH2 = CH [ CH2－CH ] n Cl Cl 19. CH≡CH + H2O 催化剂 CH3CHO

20. CaC2 + 2H2O CH≡CH↑+ Ca(OH)2 21. + Br2 Br + HBr 22. + HO－NO2 浓硫酸 NO2 +H2O

△ 催化剂 催化剂 催化剂 23. + HO－SO3H SO3H+H2O 24.

CH3 O2N + 3H2 △ CH3 NO2 NO2 催化剂

△

25. +3HO－NO2 催化剂 +3H2O 26. 3CH≡CH→

27. CH3CH2Br + H2O CH3CH2OH + HBr 28. CH3CH2Br + NaOH CH3CH2OH + NaBr 29. CH3CH2Br+ NaOH 醇 CH2 = CH2 + NaBr +H2O

△ H2O NaOH

30. 2CH3CH2OH+2Na 2CH3CH2ONa + H2↑

31. 2CH3CH2OH+O2 催化剂 2CH3CHO + 2H2O

△

32. CH3CH2OH 浓硫酸 CH2 = CH2↑+ H2O

170℃

浓硫酸 33.C2H5OH+C2H5OH C2H5OC2H5+H2O 140℃

34. OH+NaOH ONa+H2O 35. OH+H2O O－+H3O+ 36. ONa+H2O+CO2 OH+ NaHCO3

OH OH Br 37． +3Br2 Br ↓ +3HBr

Br 38. CH3CHO + H2 催化剂 CH3CH2OH △ 39. 2CH3CHO + O2 催化剂 2CH3COOH △ 40. CH3CHO+2Ag(NH3)2OH CH3COONH4+2Ag↓+3NH3+H2O

41CH3CHO+2Cu(OH)2 △ CH3COOH+Cu2O↓+2H2O

△ 42. 2CH3COOH+2Na 2CH3COONa+H2↑ 43.2CH3COOH+Na2CO3 2CH3COONa+H2O+CO2↑

44. CH3COOH+NaHCO3 CH3COONa+H2O+CO2↑

45. CH3COOH + NaOH CH3COONa + H2O

46. 2CH3COOH + Cu(OH)2 (CH3COO)2Cu + 2H2O

浓硫酸 △ 47.CH3COOH+CH3CH2OH CH3COOCH2CH3 +H2O

48. CH3COOCH2CH3+NaOH CH3COONa+CH3CH2OH 49. nOHCH2CH2COOH→ [ OCH2CH2C ] n +H2O 50. C6H12O6 (s) + 6O2 (g) 6CO2 (g) + 6H2O (l) 51. C6H12O6 催化剂 2CH3CH2OH + 2CO2 52. C12H22O11+H2O C6H12O6+ C6H12O6 蔗糖 葡萄糖 果糖

53. C12H22O11 + H2O 催化剂 2C6H12O6

麦芽唐 葡萄糖

催化剂

54. (C6H10O5)n + nH2O 催化剂 n C6H12O6 淀粉 葡萄糖 55. (C6H10O5)n + nH2O 催化剂 n C6H12O6

△

纤维素 葡萄糖

56.C17H33COO-CH2 C17H35COO-CH2

催化剂

C17H33COO-CH +3H2 C17H35COO-CH

加热、加压

C17H33COO-CH2 C17H35COO-CH2 57. C17H35COO-CH2 CH2-OH C17H35COO-CH +3NaOH 3C17H35COONa+ CH-OH C17H35COO-CH2 O CH2-OH O 58. CH2OH COOH 浓硫酸 +

CH2OH COOH △ C — C O O + 2H2O CH2－CH2 1．CH4?Cl2???CH3Cl?HCl 光CH3Cl?Cl2???CH2Cl2?HCl

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