内容发布更新时间 : 2024/12/23 21:10:22星期一 下面是文章的全部内容请认真阅读。
NaOH6. CHCHCHO稀32OCl2,H2O7.
CCH3NaOH
8. (CH3CO)2O
9.
CH3CH2C 10.
CH3ClCCH3+OH+H2OH2SO4HgSO4+H2O氢氧根SN2历程六、完成下列由反应物到产物的转变(24分,每小题4分) 1. CHCHCH32
CH2CH3BrCH3CH2CH2CH2OH2.
CH3BrNO23. CH
2CH2HOCH2CH2OCH2CH2OCH2CH2OHCH34.
5. (CH)C32 6.
CH3CH2COHCH3CH2(CH3)3CCOOHCHOC卷参考答案及评分标准
1. (S)-2-氯丁烷 2. 苯乙酮
3. 4-硝基萘酚 4. (1R,2R)-2-甲基环己醇
16
5. N-甲基-N-乙基苯胺 6.
OHCOOCH3COOCH37. 8.
CH339. CH CHCH CCH 10.
3
CH3CH3O一、选择题(20分,每题2分)
1.A 2.C 3.B 4.B 5.A 6.D 7.C 8.C 9.B 10.D 三、判断题(6分)
1、
2、
3、
4、
5、
6、
四、鉴别题(20分,各10分)
1. (10分,各2分)加入银氨配离子,白色沉淀为1-己炔,黄色沉淀为苄基溴,加入三氯化铁溶液显色的为苯酚,加入溴水褪色的为2-己炔,没反应的为2-甲基戊烷
2. (10分,各2分)
O
CH3CHCCH2CH3OHCH3CHCHCH2CH3CH3OCH3CCH3A. B. C.
CH3CHCH2CH3CH3CCH3D. CH CH E.
32CHO
五、写出下列反应的主要产物(20分) 1.
2. (CH 3)2C 3.
CH3CH2CHCH2Cl2/H2OCH3CH2CHCH2ClOHCHCH2CH3(1)O3(2)Zn粉,HO2OCH3CCH3+CH3CH2CHO+CH3ClCH3CH2CH2CH2BrC2H5OHAlCl3CH34.
MgCH3CH2CH2CH2MgBr17
CH3CH2CH2CH3+BrMgOC2H5 5.
OCH3I+HI(过量)+CH2CH2ICH3ICH2CH2OCH36. 7.
CH3CH2CHO稀 NaOHOHCH3CH2CHCHCHOCH3OCCH3Cl2,H2ONaOHCOOH+CHCl3O8.
(CH3CO)2O+CCH3OHOCCH39.
CH3CH2C 10.
+H2OH2SO4HgSO4OCH3CH2CH2CCH3O+CH3CH2CCH2CH3+CH3ClH2O氢氧根SN2历程CH3OH六、完成下列由反应物到产物的转变(20分)
1. CH3CH2CH
(1)(2)CH2BH3H2O2/氢氧根CH3CH2CH2CH2OH2.
CH3HNO3CH3加热NO2CH3BrBrNO22OHOCH2CH2OCH2CH2OCH2CH2OHHOCH2CH2OCH2CH2OCH2CH2OH3.
CH2CH2稀 冷KMnO4HOCH2CH2OHCl2/H2OClCH2CH2OHClCH2CH2OHNaOH18
4.
CH3Cl2光照O(1)CH3CCH3(2)氢CH2ClMg乙醚CH3CH2COHCH3CH2MgCl离子CH2HBr5.
6.
(CH3)2C(1)(CH3)3CBrMg(CH)CMgBr33乙醚CO2(CH3)3CCOOH(2)HO/氢离子2O(1)O3(2)Zn , H2OCOHHCHO稀-OHCH2CHOCH2CHO,-H2O 19