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习题1:
1、 求某一物流的泡、露点
已知LPG的质量分数为:乙烷5%、丙烷65%、异丁烷10%,正丁烷20%,求P为4×105Pa时的该LPG的露点温度,13kg/cm2时该LPG的泡点温度。 2、
项目
Total Flow t/h D(20℃) kg/m3
镏程 BP 10v% 20 v % 30 v % 40 v % 50 v % 60 v % 70 v% 80 v %
90 v % EP
粗汽油 75 0.7178 ℃ 44 45 54 67 80 92 105 119 136 160 194
该汽油在0.7Mp时的泡点。
某年考试题:如表所示的40℃、75t/h的汽油,需在反应器进行气相降烯烃改质反应以满足汽油排放的环保要求,反应系统压力0.7MPa,现有两股工艺热物流加热汽油,分别是10t/h 的3.5Mpa的中压蒸汽,中压蒸汽的焓值为52.4×104kcal/t,另一物流是温度为180℃,热负荷为650×104Kcal 的化工轻油,请问现有条件能否实现汽油的气相进料,完成降烯烃改质反应。
某年考试题:已知LPG的质量分数为:丙烷25.5%、异丁烷15.0%,正丁烷49.5%,正戊烷10.0%,供气压力为0.15MPa,有些企业为牟取利益,在该LPG中掺混低廉的二甲醚25%出售,当有液体存在时,就会腐蚀垫片,问在该供气压力下掺混二甲醚后的LPG什么条件下会出现腐蚀垫片现象。
某年考试题:下表是我国第二个LNG接收站福建莆田LNG的组成,该LNG来自印尼东固气田,此天然气组成的临界压力PC为50.55bar,求该组成的临界温度。
福建莆田 LNG 组成
组分 Mol%
CH4 96.64 C2H6 1.97 C3H8 0.34 i-C4H10 0.07 n-C4H10 0.08 N2 0.9 某年考试题:1000 kg/hr的纯二氯乙烷(CH2CL-CH2Cl)高温裂解反应生成氯乙烯单体(CHCl=CH2)和氯化氢(HCl),从反应器出来的裂解气组成:氯乙烯为35.5 mol%、HCl 35.5 mol%,原料二氯乙烷为29 mol%,压力为27kg/cm2的热气体需过冷(过冷度为10℃)经精馏塔来提纯氯乙烯,问该裂解气进分馏塔的温度为多少? 3、
OVHDFEEDCOLUMBTMS
Part A
Perform a rating calculation of a methanol tower using the following specifications:
Feed to column: ? 36.8 wt% methanol ? 63.2 wt% water
? Total flowrate of 120000 lb/hr ? Saturated liquid at 18 psia Column specifications:
? Column tray=38 (exclude condenser & reboiler) ? Feed tray=23
? Liquid distillation and bottoms ? Top-stage pressure=16.1 psia ? Pressure drop per stage=0.1 psia ? Distillate flowrate=1245 lbmol/hr ? Molar reflux ratio=1.3 Part B
Perform a design calculation for the above column. Set up design specifications within
the column so that the following objectives are met:
? 99.95 wt% methanol in the distillate; ? 99.90 wt% water in the bottoms.
To achieve these specs, you can vary:
? The distillate rate from 800 lbmol/hr to 1700 lbmol/hr; ? The reflux ratio from 0.8 to 2. Part C
Perform the same design calculation after specifying a 65% Murphree efficiency for each tray. Assume the condenser and reboiler have stage efficiency of 90%.
How do these efficiencies affect the condenser and reboiler duties of the column? Part D
Perform a tray sizing calculation for the entire column, given that buttle cap tray are used. Number of passes=1;
Tray spacing= 2ft
Fractional approach to flooding less than or equal to 0.8 Part E
Perform a tray rating calculation for the entire column, given that buttle cap tray are used. Number of passes=1; Column diameter=7.5ft Tray spacing= 2ft Part F
Draw heating/cooling curves in the condenser and reboiler.