1
1
缁?/p>
璁?/p>
1.1
鍦ㄩ摱鍌寲鍓備笂杩涜鐢查唶姘у寲涓虹敳閱涚殑鍙嶅簲锛?/p>
杩涘叆鍙嶅簲鍣ㄧ殑鍘熸枡姘斾腑锛岀敳閱囷細绌烘皵锛氭按钂告皵
=2
锛?/p>
4
锛?/p>
1.3
锛堟懇灏旀瘮锛夛紝鍙嶅簲
鍚庣敳閱囩殑杞寲鐜囪揪
72%
锛岀敳閱涚殑鏀剁巼涓?/p>
69.2%
銆傝瘯璁＄畻
锛?/p>
1
锛?/p>
锛?/p>
1
锛?/p>
鍙嶅簲鐨勯�夋嫨鎬э紱
锛?/p>
2
锛?/p>
锛?/p>
2
锛?/p>
鍙嶅簲鍣ㄥ嚭鍙ｆ皵浣撶殑缁勬垚銆?/p>
瑙ｏ細锛?/p>
1
锛夌敱锛?/p>
1.7
锛夊紡寰楀弽搴旂殑閫夋嫨鎬т负锛?/p>
锛?/p>
2
锛夎繘鍏ュ弽搴斿櫒鐨勫師鏂欐皵涓紝鐢查唶锛氱┖姘旓細姘磋捀姘?/p>
=2
锛?/p>
4
锛?/p>
1.3
锛堟懇灏旀瘮锛夛紝
杩涘叆鍙嶅簲鍣ㄧ殑鎬诲師鏂欓噺涓?/p>
100mol
鏃讹紝鍒欏弽搴斿櫒鐨勮繘鏂欑粍鎴愪负路
缁勫垎
鎽╁皵鍒嗙巼
y
i0
鎽╁皵鏁?/p>
n
i0
(mol)
CH
3
OH
2/
锛?/p>
2+4+1.3
锛?/p>
=0.2740
27.40
绌烘皵
4/
锛?/p>
2+4+1.3
锛?/p>
=0.5479
54.79
姘?/p>
1.3/
锛?/p>
2+4+1.3
锛?/p>
=0.1781
17.81
鎬昏
1.000
100.0
璁剧敳閱囩殑杞寲鐜囦负
X
A
锛岀敳閱涚殑鏀剁巼涓?/p>
Y
P
锛屾牴鎹紙
1.3
锛夊拰锛?/p>
1.5
锛夊紡鍙緱鍙嶅簲鍣?/p>
鍑哄彛鐢查唶銆佺敳閱涘拰浜屾哀鍖栫⒊鐨勬懇灏旀暟
n
A
銆?/p>
n
P
鍜?/p>
n
c
鍒嗗埆涓猴細
n
A
=n
A0
(1-X
A
)=7.672 mol
n
P
=n
A0
Y
P
=18.96 mol
n
C
=n
A0
(X
A
-Y
P
)=0.7672 mol
缁撳悎涓婅堪鍙嶅簲鐨勫寲瀛﹁閲忓紡锛屾按锛?/p>
n
W
锛夈�佹哀姘旓紙
n
O
锛夊拰姘皵锛?/p>
n
N
锛夌殑鎽╁皵鏁板垎鍒?/p>
涓猴細
n
W
=n
W0
+n
P
+2n
C
=38.30 mol
n
O
=n
O0
-1/2n
P
-3/2n
C
=0.8788 mol
n
N
=n
N0
=43.28 mol
鎵�浠ワ紝鍙嶅簲鍣ㄥ嚭鍙ｆ皵浣撶粍鎴愪负锛?/p>
缁勫垎
鎽╁皵鏁帮紙
mol
锛?/p>
鎽╁皵鍒?
鐜?/p>
%
CH
3
OH
7.672
6.983
HCH
O
18.96
17.26
H
2
O
38.3
34.87
CO
2
0.7672
0.6983
O
2
0.8788
0.7999
N
2
43.28
39.39