绗崄涓�绔?/p>
鍖栧鍔ㄥ姏瀛﹀熀纭�
(1)
缁冧範棰?/p>
涓�銆佸垽鏂锛?/p>
1
锛?/p>
鍦ㄥ悓涓�鍙嶅簲涓悇鐗╄川鐨勫彉鍖栭�熺巼鐩稿悓銆?/p>
2
锛庤嫢鍖栧鍙嶅簲鐢变竴绯诲垪鍩哄厓鍙嶅簲缁勬垚锛屽垯璇ュ弽搴旂殑閫熺巼鏄悇鍩哄厓鍙嶅簲閫熺巼鐨勪唬鏁板拰銆?/p>
3
锛?/p>
鍗曞垎瀛愬弽搴斾竴瀹氭槸鍩哄厓鍙嶅簲銆?/p>
4
锛?/p>
鍙屽垎瀛愬弽搴斾竴瀹氭槸鍩哄厓鍙嶅簲銆?/p>
5
锛?/p>
闆剁骇鍙嶅簲鐨勫弽搴旈�熺巼涓嶉殢鍙嶅簲鐗╂祿搴﹀彉鍖栬�屽彉鍖栥�?/p>
6
锛?/p>
鑻ヤ竴涓寲瀛﹀弽搴旀槸涓�绾у弽搴旓紝鍒欒鍙嶅簲鐨勯�熺巼涓庡弽搴旂墿娴撳害鐨勪竴娆℃柟鎴愭姣斻�?/p>
7
锛?/p>
涓�涓寲瀛﹀弽搴旇繘琛屽畬鍏ㄦ墍闇�鐨勬椂闂存槸鍗婅“鏈熺殑
2
鍊嶃�?/p>
8
锛?/p>
涓�涓寲瀛﹀弽搴旂殑绾ф暟瓒婂ぇ锛屽叾鍙嶅簲閫熺巼涔熻秺澶с�?/p>
9
锛?/p>
鑻ュ弽搴?/p>
A + B
Y + Z
鐨勯�熺巼鏂圭▼涓猴細
r
=
kc
A
c
B
锛屽垯璇ュ弽搴旀槸浜岀骇鍙嶅簲锛屼笖鑲畾涓?/p>
鏄弻鍒嗗瓙鍙嶅簲銆?/p>
10.
涓嬪垪璇存硶鏄惁姝ｇ‘锛?/p>
(1)
H
2
+I
2
=2HI
鏄?/p>
2
鍒嗗瓙鍙嶅簲锛?/p>
(2)
鍗曞垎瀛愬弽搴旈兘鏄竴绾у弽搴旓紝鍙屽垎瀛愬弽搴旈兘鏄簩绾у弽
搴斻�?/p>
锛?/p>
(3)
鍙嶅簲绾ф暟鏄暣鏁扮殑涓虹畝鍗曞弽搴?/p>
(4)
鍙嶅簲绾ф暟鏄垎鏁扮殑涓哄鏉傚弽搴斻�?/p>
11
锛?/p>
瀵逛簬涓�鑸湇浠庨樋绱凹涔屾柉鏂圭▼鐨勫寲瀛﹀弽搴旓紝娓╁害瓒婇珮锛屽弽搴旈�熺巼瓒婂揩锛屽洜姝ゅ崌楂樻俯
搴︽湁鍒╀簬鐢熸垚鏇村鐨勪骇鐗┿�?/p>
12
锛?/p>
鑻ュ弽搴?/p>
(1)
鐨勬椿鍖栬兘涓?/p>
E
1
锛屽弽搴?/p>
(2)
鐨勬椿鍖栬兘涓?/p>
E
2
锛屼笖
E
1
>
E
2
锛屽垯鍦ㄥ悓涓�娓╁害涓?/p>
k
1
涓�
瀹氬皬浜?/p>
k
2
銆?/p>
13
锛?/p>
鑻ユ煇鍖栧鍙嶅簲鐨?/p>
螖
r
U
m
< 0
锛屽垯璇ュ寲瀛﹀弽搴旂殑娲诲寲鑳藉皬浜庨浂銆?/p>
14
锛?/p>
瀵瑰钩琛″弽搴?/p>
A
Y
锛屽湪涓�瀹氭俯搴︿笅鍙嶅簲杈惧钩琛℃椂锛屾閫嗗弽搴旈�熺巼甯告暟鐩哥瓑銆?/p>
15
锛?/p>
骞宠鍙嶅簲
C
B
A
2
1
飩撅偖
飩?/p>
飩撅偖
飩?/p>
k
k
鈹?/p>
锛?/p>
k
1
/
k
2
鐨勬瘮鍊间笉闅忔俯搴︾殑鍙樺寲鑰屽彉鍖栥�?/p>
16
锛?/p>
澶嶆潅鍙嶅簲鐨勯�熺巼鍙栧喅浜庡叾涓渶鎱㈢殑涓�姝ャ�?/p>
17
锛?/p>
鍙嶅簲鐗╁垎瀛愮殑鑳介噺楂樹簬浜х墿鍒嗗瓙鐨勮兘閲忥紝鍒欐鍙嶅簲灏变笉闇�瑕佹椿鍖栬兘銆?/p>
18
锛?/p>
娓╁害鍗囬珮銆傛銆侀�嗗弽搴旈�熷害閮戒細澧炲ぇ锛屽洜姝ゅ钩琛″父鏁颁篃涓嶉殢娓╁害鑰屾敼鍙樸�?/p>
浜屻�佸崟閫夐锛?/p>
1
锛?/p>
鍙嶅簲
3O
2
2O
3
锛屽叾閫熺巼鏂圭▼
-
d[O
2
]/d
t
=
k
[O
3
]
2
[O
2
]
鎴?/p>
d[O
3
]/d
t
=
k
'[O
3
]
2
[O
2
]
锛岄偅
涔?/p>
k
涓?/p>
k
'
鐨勫叧绯绘槸锛?/p>
(A)
2
k
= 3
k
'
锛?/p>
(B)
k
=
k
'
锛?/p>
(C)
3
k
= 2
k
'
锛?/p>
(D)
陆
k
= 鈪?/p>
k
'
銆?/p>
2
锛?/p>
鏈夊涓嬬畝鍗曞弽搴?/p>
a
A +
b
B
dD
锛屽凡鐭?/p>
a
<
b
<
d
锛屽垯閫熺巼甯告暟
k
A
銆?/p>
k
B
銆?/p>
k
D
鐨勫叧绯讳负锛?/p>
(A)
d
k
b
k
a
k
D
B
A
锛?/p>
锛?/p>
锛?/p>
(B)
k
A
<
k
B
<
k
D
锛?/p>
(C)
k
A
>
k
B
>
k
D
锛?/p>
(D)
d
k
b
k
a
k
D
B
A
锛?/p>
锛?/p>
銆?/p>
3
锛?/p>
鍏充簬鍙嶅簲閫熺巼
r
锛岃〃杈句笉姝ｇ‘鐨勬槸锛?/p>
(A)
涓庝綋绯荤殑澶у皬鏃犲叧鑰屼笌娴撳害澶у皬鏈夊叧
锛?/p>
(B)
涓庡悇鐗╄川娴撳害鏍囧害閫夋嫨鏈夊叧
锛?/p>
(C)
鍙负姝ｅ�间篃鍙负璐熷�?/p>
锛?/p>
(D)
涓庡弽搴旀柟绋嬪紡鍐欐硶鏃犲叧
銆?/p>
4
锛?/p>
杩涜鍙嶅簲
A + 2D
3G
鍦?/p>
298K
鍙?/p>
2dm
3
瀹瑰櫒涓繘琛岋紝鑻ユ煇鏃跺埢鍙嶅簲杩涘害闅忔椂闂村彉
鍖栫巼涓?/p>
0.3 mol路
s
-
1
锛屽垯姝ゆ椂
G
鐨勭敓鎴愰�熺巼涓?/p>
(
鍗曚綅锛?/p>
mol路
dm
锛?/p>
3
路
s
-
1
)
锛?/p>
(A)
0.15
锛?/p>
(B)
0.9
锛?/p>
(C)
0.45
锛?/p>
(D)
0.2
銆?/p>
5
锛?/p>
鍩哄厓鍙嶅簲浣撶郴
a
A +
d
D
g
G
鐨勯�熺巼琛ㄨ揪寮忎腑锛屼笉姝ｇ‘鐨勬槸锛?/p>
(A)
-
d[A]/d
t
=
k
A
[A]
a
[D]
d
锛?/p>
(B)
-
d[D]/d
t
=
k
D
[A]
a
[D]
d
锛?/p>
(C)
d[G]/d
t
=
k
G
[G]
g
锛?/p>
(D)
d[G]/d
t
=
k
G
[A]
a
[D]
d
銆?/p>
6
锛?/p>
鏌愪竴鍙嶅簲鍦ㄦ湁闄愭椂闂村唴鍙弽搴斿畬鍏紝鎵�闇�鏃堕棿涓?/p>
c
0
/
k
锛岃鍙嶅簲绾ф暟涓猴細
(A)
闆剁骇
锛?/p>
(B)
涓�绾?/p>
锛?/p>
(C)
浜岀骇
锛?/p>
(D)
涓夌骇
銆?/p>
7
锛?/p>
鏌愪竴鍩哄厓鍙嶅簲锛?/p>
2A(g) + B(g)
E(g)
锛屽皢
2mol
鐨?/p>
A
涓?/p>
1mol
鐨?/p>
B
鏀惧叆
1
鍗囧鍣ㄤ腑娣?/p>
鍚堝苟鍙嶅簲锛岄偅涔堝弽搴旂墿娑堣�椾竴鍗婃椂鐨勫弽搴旈�熺巼涓庡弽搴旇捣濮嬮�熺巼闂寸殑姣斿�兼槸锛?/p>